@article { author = {}, title = {SYNTHESIS OF NORBORNENE FURYL ESTERS AND THEIR ENZYMATIC KINETIC RESOLUTION BY PIG LIVER ESTRASE (PLE)}, journal = {Journal of Sciences, Islamic Republic of Iran}, volume = {10}, number = {3}, pages = {-}, year = {1999}, publisher = {University of Tehran}, issn = {1016-1104}, eissn = {2345-6914}, doi = {}, abstract = {The reaction of furylacrylic acid with cyclopentadiene in toluene gave the expected Diels-Alder endo-and exo-adductsin -1 : 1 ratio. The adducts were separated by iodolactonization method to provide 3-endo-(2'-furyl) bicyclo 12.2.11 hept-5-ene- 2-exo-carboxylic acid and 3-exo-(2'-fury1)bicyclo 12.2.11 hept-5-ene-2-endocarboxylic acid. Esterification of these acids by MeI / HMPA gave the expected methyl esters. Kinetic resolution of racemic endo- and exo-ester adducts by PLE(phosphate buffer, pH, 8) provided the related optically active isomers}, keywords = {}, url = {https://jsciences.ut.ac.ir/article_31432.html}, eprint = {https://jsciences.ut.ac.ir/article_31432_18f26ff37fcce3eceb53fca8faa24757.pdf} }