%0 Journal Article %T LITHIUM PERCHLORATE MEDIATED AMINATION REACTION OF ALDEHYDES: A NOVEL METHOD FOR SYNTHESIS OF N, N-DIALKYL-p-SILYLATED AMINES* %J Journal of Sciences, Islamic Republic of Iran %I University of Tehran %Z 1016-1104 %D 1995 %\ 08/01/1995 %V 6 %N 3 %P - %! LITHIUM PERCHLORATE MEDIATED AMINATION REACTION OF ALDEHYDES: A NOVEL METHOD FOR SYNTHESIS OF N, N-DIALKYL-p-SILYLATED AMINES* %R %X P-Silylated N,N-dialkyl amines (5) were easily synthesized in good to excellent yield from aldehydes (1), trimethylsilyldialkylamines (2), and trimethylsilylmethylmagnesium chloride (4) in the presence of 5 M lithium perchlorate solution in diethyl ether. The reaction Of (2) with aldehyde proceeded smoothly in the LiCI0 , to give the imimum salt (3). Addition of trimethylsilylmethylrnagnesium chloride (4) gave the desired product %U https://jsciences.ut.ac.ir/article_31338_608334d9d8a3c8cdef9532da9b190fb6.pdf