TY - JOUR ID - 31815 TI - THE DEALKYLATION OF TERTIARY AMINES WITH THIOPHOSGENE AND 1-CHLOROETHYL CHLOROTHIONOFORMATE JO - Journal of Sciences, Islamic Republic of Iran JA - JSCIENCES LA - en SN - 1016-1104 Y1 - 2001 PY - 2001 VL - 12 IS - 1 SP - EP - DO - N2 - Thiophosgene and 1-chloroethyl chlorothionoformate react readily with tertiary amines, and give the dialkylamine hydrochloride after hydrolysis of the initial product with water. Benzyl and allyl groups are cleaved in preference to methyl and other alkyl groups. The rection with the isoquinoline alkaloid narcotine occurs particularly easily. UR - https://jsciences.ut.ac.ir/article_31815.html L1 - https://jsciences.ut.ac.ir/article_31815_a5850567794cd9b21bb5950729b85132.pdf ER -