Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of Iran
Abstract
Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions.
Farzaneh,F and Hamidipour,L . (2016). Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes. Journal of Sciences, Islamic Republic of Iran, 27(1), 31-37.
MLA
Farzaneh,F , and Hamidipour,L . "Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes", Journal of Sciences, Islamic Republic of Iran, 27, 1, 2016, 31-37.
HARVARD
Farzaneh F, Hamidipour L. (2016). 'Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes', Journal of Sciences, Islamic Republic of Iran, 27(1), pp. 31-37.
CHICAGO
F Farzaneh and L Hamidipour, "Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes," Journal of Sciences, Islamic Republic of Iran, 27 1 (2016): 31-37,
VANCOUVER
Farzaneh F, Hamidipour L. Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes. J. Sci. I. R. I.. 2016;27(1):31-37.
Journal of Sciences, Islamic Republic of Iran