Farzaneh, F., Hamidipour, L. (2016). Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes. Journal of Sciences, Islamic Republic of Iran, 27(1), 31-37.
F. Farzaneh; L. Hamidipour. "Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes". Journal of Sciences, Islamic Republic of Iran, 27, 1, 2016, 31-37.
Farzaneh, F., Hamidipour, L. (2016). 'Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes', Journal of Sciences, Islamic Republic of Iran, 27(1), pp. 31-37.
Farzaneh, F., Hamidipour, L. Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes. Journal of Sciences, Islamic Republic of Iran, 2016; 27(1): 31-37.
Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes
Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of Iran
Receive Date: 29 August 2015,
Revise Date: 25 October 2015,
Accept Date: 30 November 2015
Abstract
Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions.
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