Abstract
The reaction of PbCI, with 1,4,10,13-tetra-oxa-7, 16-diaza-cyclooctadecane (L=
C H N O ) yielded colourless crystals of LPbCI . The complex crystallizes in
monoclinic space group, C2/c, a = 7.90(2), b = 14.75(3) and C = 17.36(3) ?= ?
101.75(3)?, Z = 4 and R = 0.083 The coordination number around the lead atom is
Eight . [Pb-N, 2.36(1), 2.70(4)], [Pb-0,2.41(3)-2.57(3)], [Pb-CI, 2.51(4), 2.57(4)].
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