Journal of Sciences, Islamic Republic of Iran

Current Issue

By Issue

By Author

By Subject

Author Index

Keyword Index

About Journal

Aims and Scope

Editorial Board

Publication Ethics

Indexing and Abstracting

Related Links

FAQ

Peer Review Process

Journal Metrics

News

Synthesis of Fe-doped CeO2 Nanoparticles Prepared by Solgel Method

Document Type : Original Paper

Authors

Department of Physics, Varamin Pishva Branch, Islamis Azad University, Varamin, Iran

Abstract

Nanomaterials have achieved remarkable technological advances in bulk materials due to their excellent physical, chemical and biological properties. cerium oxide (CeO2) nanostructured doped with Fe ions is attractive due to improvement in redox properties, transport property and surface-to-volume ratio. In this research, Fe-doped CeO2 nanoparticles (NPs) were prepared by simple solgel method. The as-synthesized and annealed samples were studied by transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD). The XRD result revealed the cubic crystal structure of Fe-doped CeO2 NPs. The FESEM images showed that the uniformity of the NPs increase with increasing calcination temperature. The TEM studies demonstrated the 20 nm uniform NPs.

Keywords

References
  1. Zarinkamar M., Farahmandjou M. and Firoozabadi T.P. Diethylene Glycol-Mediated Synthesis of Nano-Sized Ceria (CeO2) Catalyst. Nanostruct. 6: 116-120 (2016).
  2. Farahmandjou M. and Khalili P. Morphology Study of anatase nano-TiO2 for Self-cleaning Coating. J. Fund. Phys. Sci. 3: 54-56 (2013).
  3. Ramazani M., Farahmandjou M. and T.P. Fabrication and Characterization of Rutile TiO2 Nanocrystals by Water Soluble Precursor. Phys. Chem. Res. 3: 293-298 (2015).
  4. Khoshnevisan B., Marami M.B. and Farahmandjou M. Fe3+-Doped Anatase TiO2 Study Prepared by New Sol-Gel Precursors. Phys. Lett. 35: 027501-5 (2018).
  5. Marami M.B., Farahmandjou M. and Khoshnevisan B. Solgel Synthesis of Fe-doped TiO2 J. electron. Mater. 47: 3741-3748 (2018).
  6. Jafari, A., Khademi S. and Farahmandjou M. Nano-crystalline Ce-doped TiO2 Powders: Sol-gel Synthesis and Optoelectronic Properties. Res. Express. 2018, 5: 095008 (2018).
  7. Farahmandjou M. and Khalili P. Study of Nano SiO2/TiO2 Superhydrophobic Self-Cleaning Surface Produced by Sol-Gel. J. Basic. Appl. Sci. 2013, 7: 462-465 (2013).
  8. S., Farahmandjou M. and Firoozabadi T.P. Sol-gel synthesis of zinc oxide (ZnO) nanoparticles: study of structural and optical properties. J. Sci. I. R. Iran. 26: 281-285 (2015).
  9. Farahmandjou M. and Dastpak M. Fe-Loaded CeO2 Nanosized Prepared by Simple Co-Precipitation Route. Chem. Res. 6: 713-720 (2018).
  10. Farahamndjou M. The study of electro-optical properties of nanocomposite ITO thin films prepared by e-beam evaporation. Mex. Fís. 59: 205-207 (2013).
  11. Akhtari F., Zorriasatein S., Farahmandjou M. and Elahi S.M. Structural, optical, thermoelectrical, and magnetic study of Zn1-xCoxO (0 ≤ x ≤ 0.10) nanocrystals. J. Appl. Ceram. Technol. 15: 723-733 (2018).
  12. Akhtari F., Zorriasatein S., Farahmandjou M. and Elahi S.M. Synthesis and optical properties of Co2+-doped ZnO Network prepared by new precursors. Res. Express. 5: 065015 (2018).
  13. Farahmandjou M. and Golabiyan N. Solution combustion preparation of nano-Al2O3: synthesis and characterization. Phenom. Nano. Micro. Scales. 3: 100-105 (2015).
  14. Farahmandjou M. Synthesis of ITO Nanoparticles Prepared by Degradation of Sulfide Method. Phys. Lett. 29: 077306-9 (2012).
  15. Farahmandjou M. and Golabiyan N. Synthesis and characterization of Alumina (Al2O3) nanoparticles prepared by simple sol-gel method. J. Bio-Inorg. Hybr. Nanomater. 5: 73-77 (2016).
  16. Jurablu S., Farahmandjou M. and Firoozabadi T.P. Multiple-layered structure of obelisk-shaped crystalline nano-ZnO prepared by sol–gel route. Theoretical. Appl. Phys. 9: 261–266 (2015).
  17. Dastpak M., Farahmandjou M. and Firoozabadi T.P. Synthesis and preparation of magnetic Fe-doped CeO2 nanoparticles prepared by simple sol-gel method. Supercond Nov. Magn. 29: 2925-2929 (2016).
  18. Motaghi S.and Farahmandjou M. Structural and optoelectronic properties of Ce-Al2O3 nanoparticles prepared by sol-gel precursors. Res. Express. 6: 045008 (2019).
  19. Zarinkamar M., Farahmandjou M. and Firoozabadi T.P. One-step synthesis of ceria (CeO2) nano-spheres by a simple wet chemical method. Ceram. Proc. Res. 17: 166-169 (2016).
  20. Farahmandjou M.and Soflaee F.Synthesis of Iron Oxide Nanoparticles using Borohydride Reduction. J. Bio-Inorg. Hybr. Nanomater. 3: 203-206 (2014).
  21. Farahmandjou M. and Salehizadeh S.A. The optical band gap and the tailing states determination in glasses of TeO2-V2O5-K2O system. Glass Phys. Chem. 39: 473-479 (2013).
  22. A Khodadadi, M Farahmandjou, M Yaghoubi, AR Amani. Structural and optical study of Fe3+‐doped Al2O3 nanocrystals prepared by new sol gel precursors. J. Appl. Ceram. Technol. 16: 718-726 (2019).
  23. Honarbakhsh S., Farahmandjou M. and Behroozinia S. Synthesis and characterization of iron cobalt (FeCo) nanorods prepared by simple Co-precipitation method. Fund. Appl. Sci. 8: 892-900 (2016).
  24. Behrouzinia S., Salehinia D., Khorasani K. and Farahmandjou M. The continuous control of output power of a CuBr laser by a pulsed external magnetic field. Commun. 436: 143-145 (2019).
  25. Farahmandjou M. and Motaghi S. Sol-gel Synthesis of Ce-doped α-Al2O3: Study of Crystal and Optoelectronic Properties. Commun. 441: 1–7 (2019).
  26. Jafari A., Khademi S., Farahmandjou M., Darudi A. and Rasuli R. Structural and optical properties of Ce3+-doped TiO2 nanocrystals prepared by sol-gel precursors. Electron. Mater. 47: 6901–6908 (2018).
  27. Khodadadi A., Farahmandjou M. and Yaghoubi M. Investigation on synthesis and characterization of Fe-doped Al2O3 nanocrystals by new sol–gel precursors. Res. Express. 6: 025029 (2019).
  28.  

 
  • Farahmandjou M. and Soflaee F. Polymer-Mediated Synthesis of Iron Oxide (Fe2O3) Nanorods. J. Phys. 53: 080801-9 (2015).
  1. Farahmandjou M. and Soflaee F. Synthesis and characterization of α-Fe2O3 nanoparticles by simple co-precipitation method. Chem. Res. 3: 193-198 (2015).
  2. Farahmandjou M. Magnetocrystalline properties of Iron-Platinum (L10-FePt) nanoparticles through phase transition. J. Phys. Res. 16: 1-5 (2016).
  3. Shadrokh S., Farahmandjou M. and Firozabadi T.P. Fabrication and Characterization of Nanoporous Co Oxide (Co3O4) Prepared by Simple Sol-gel Synthesis. Chem. Res. 4: 153-160 (2016).
  4. Farahmandjou M., Honarbakhsh S. and Behrouzinia S. PVP-Assisted Synthesis of Cobalt Ferrite (CoFe2O4) Nanorods. Chem. Res. 4: 655-662 (2016).
  5. Farahmandjou M. Synthesis and Structural Study of L10- FePt nanoparticles. J. Engin. Environ. Sci. 34: 265-270 (2010).
  6. Farahmandjou M., Honarbakhsh S. and Behrouzinia S. FeCo Nanorods Preparation Using New Chemical Synthesis. Supercond. Nov. Magn. 31: 4147–4152 (2018).
  7. Farahmandjou M. Effect of oleic acid and oleylamine surfactants on the size of FePt nanoparticles. Supercond. Nov. Magn. 25: 2075-2079 (2012).
  8. Sebt S.A., Parhizgar S.S., Farahmandjou M., Aberomand P. and Akhavan M. The role of ligands in the synthesis of FePt nanoparticles.  Supercond. Nov. Magn. 22: 849-854 (2009).
  9. Steele B.C.H. Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C. State. Ion. 129: 95-110 (2000).
  10. Bao H., Chen X., Fang J., Jiang Z. and Huang W. Structure-activity relation of Fe2O3–CeO2 composite catalysts in CO oxidation. Lett. 125: 160-167 (2008).
  11. Tessier F. Chevré F. Munoz F., Merrdignac Conanec O., Marchand R.,  M. and Colbeau Justin C. Powder preparation and UV absorption properties of selected compositions in the CeO2–Y2O3 system.  J. Solid State Chem. 181: 1204-1212 (2008).
  12. Higashi K., Sonoda K., Ono H., Sameshima S. and Hirata Y. Characterization of Rare-Earth-Doped Ceria Powders Derived from Oxalate Coprecipitate. Key Eng. Mater. 25: 159-160 (1999).
  13.  Zhang T.,  Hing P., Huang H. and  Kilner J. Densification, microstructure and grain growth in the CeO2–Fe2O3 system (0⩽Fe/Ce⩽20%). Eur. Ceram. Soc. 21: 2221-2228 (2001).
  14. Zhang T.S., Ma J., Kong L.B., Zeng Z.Q., Hing P. and Kilner J.A. Final-stage sintering behavior of Fe-doped CeO2. Sci. Eng. B. 103: 177-183 (2003).
  15. Scherrer P. Bestimmung der Grosse und der Inneren Struktur von Kolloidteilchen Mittels Rontgenstrahlen. Nachr. V. d. Gesellsch. d. Wissensch..Math. Phys. Kl. Gotting.2: 98-100 (1918).
Journal of Sciences, Islamic Republic of Iran
Volume 31, Issue 1
March 2020
Pages 39-43
Files
Share
How to cite
Statistics