Document Type : Original Paper
Authors
1 1 Department of Physical Chemistry and Nanochemistry, Faculty of Chemistry, Alzahra University, Tehran, Islamic Republic of Iran
2 2 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran
Abstract
Single crystals of a new coordination polymer, {[Zn(2,2’-bipyridine)(H2O)2(1,5-NDS)].2H2O}, where 1,5-NDS is 1,5-naphthalenedisulfonate ion, have been successfully grown under hydrothermal conditions. The as-synthesised coordination polymer was characterised by X-ray Diffraction analysis which shows that the metal centres have been linked by 1,5-NDS linkers and then the structure has extended in a 1D chain. Moreover, the compound was studied using thermogravimetric analysis (TGA) to check its thermal stability and IR spectroscopy. The prepared compound was a good candidate as a precursor to prepare ZnO nanoparticles. ZnO nanoparticles which were achieved after calcinating the compound, were characterized by Scanning Electron Microscopy (SEM) and PXRD.
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- Alamgholiloo H, Zhang S, Ahadi A, Rostamnia S, Banaei R, Li Z et al. Synthesis of bimetallic 4-PySI-Pd@ Cu (BDC) via open metal site Cu-MOF: effect of metal and support of Pd@ Cu-MOFs in H2 generation from formic acid. J. Mol. Catal. 2019 Apr 1;467:30-7.
- Abou-Elyazed AS, Ye G, Sun Y, El-Nahas AM. A series of UiO-66 (Zr)-structured materials with defects as heterogeneous catalysts for biodiesel production Ind. Eng. Chem. Res. 2019 Nov 7;58(48):21961-71.
- Hendon CH, Rieth AJ, Korzynski MD, Dinca M. Grand challenges and future opportunities for metal–organic frameworks. ACS Cent. Sci. 2017 Jun 28;3(6):554-63.
- Engel ER, Scott JL. Advances in the green chemistry of coordination polymer materials. Green Chem. 2020;22(12):3693-715.
- Ranjbar M, Pardakhty A, Amanatfard A, Asadipour A. Efficient drug delivery of β-estradiol encapsulated in Zn-metal–organic framework nanostructures by microwave-assisted coprecipitation method. Drug Des. Devel. Ther. 2018;12:2635.
- Gan YL, Huang KR, Li YG, Qin DP, Zhang DM, Zong ZA et al. Synthesis, structure and fluorescent sensing for nitrobenzene of a Zn-based MOF. Mol. Struct. 2021 Jan 5;1223:129217.
- Lu K, Aung T, Guo N, Weichselbaum R, Lin W. Nanoscale metal–organic frameworks for therapeutic, imaging, and sensing applications. Adv.Mater. 2018 Sep;30(37):1707634.
- Teo WL, Zhou W, Qian C, Zhao Y. Industrializing metal–organic frameworks: Scalable synthetic means and their transformation into functional materials. Mater.Today. 2021 Jul 1;47:170-86.
- Tseng TW, Luo TT, Kan SJ, Nguyen DD. Auxiliary ligand-modulated trisimidazole-based coordination polymers: syntheses, structures and photoluminescence properties. CrystEngComm. 2021;23(19):3434-43.
- Griffin SL, Champness NR. A periodic table of metal-organic frameworks. Chem. Rev. 2020 Jul 1;414:213295.
- Hussain MZ, Yang Z, Huang Z, Jia Q, Zhu Y, Xia Y. Recent advances in metal–organic frameworks derived nanocomposites for photocatalytic applications in energy and environment. Adv. Sci. 2021 Jul;8(14):2100625.
- Lippi M, Cametti M. Highly dynamic 1D coordination polymers for adsorption and separation applications. Coord. Chem. Rev. 2021 Mar 1;430:213661.
- Ahmad M, Siddiqui KA. 0D+ 1D= 1D Zn-orotate-Bimb polyrotaxane coordination polymer: Synthesis, structure, thermogravimetric and variable temperature luminescence analysis. Polyhedron. 2022 Mar 15;215:115693.
- Feng Y, Li P, Wei J. Engineering functional mesoporous materials from plant polyphenol based coordination polymers. Coord. Chem. Rev. 2022 Oct 1;468:214649.
- Thuéry P, Atoini Y, Harrowfield J. The sulfonate group as a ligand: A fine balance between hydrogen bonding and metal ion coordination in uranyl ion complexes. Dalton Trans. 2019;48(24):8756-72.
- Mohanty A, Singh UP, Ghorai A, Banerjee S, Butcher RJ. Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies. CrystEngComm. 2021;23(3):684-93.
- Xie WP, Wang N, Long Y, Ran XR, Gao JY, Chen CJ et al. Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2, 7-naphthalenedisulfonate and isonicotinic acid: Structure, luminescence, and magnetic properties. Chem. Commun. 2014 Feb 1;40:151-6.
- Prasad SS, Sudarsanakumar MR, Dhanya VS, Suma S, Kurup MP. Synthesis and characterization of a prominent NLO active MOF of lead with 1, 5-naphthalenedisulfonic acid. Mol. Struct. 2018 Sep 5;1167:134-41.
- Geranmayeh S, Abbasi A, Zarnani AH, Skripkin MY. A novel trinuclear zinc metal–organic network: Synthesis, X-ray diffraction structures, spectroscopic and biocompatibility studies. Polyhedron. 2013 Sep 18;61:6-14.
- Nimmermark A, Öhrström L, Reedijk J. Metal-ligand bond lengths and strengths: are they correlated? A detailed CSD analysis.
- Tai XS, Zhang YP, Zhao WH. Synthesis, crystal structure and antitumor activity of a dinuclear calcium complex based on 1, 5-naphthalenedisulfonate and 2, 2′-bipyridine ligands. Chem. Intermed. 2015 Jul;41(7):4339-47.
- Kim YI, Yun SJ, Hwang IH, Kim DY, Kang SK. Bis (2-{[(9H-fluoren-2-yl) methylidene] amino} phenolato-κ2N, O) zinc methanol disolvate. Acta Crystallogr. E: Structure Reports Online. 2012 Apr 1;68(4):m504-5.
- Perles J, Snejko N, Iglesias M, Monge MÁ. 3D scandium and yttrium arenedisulfonate MOF materials as highly thermally stable bifunctional heterogeneous catalysts. J. Mater. Chem. 2009;19(36):6504-11.
- Chen CH, Cai J, Liao CZ, Feng XL, Chen XM, Ng SW. Variation in the coordination mode of arenedisulfonates: syntheses and structural characterization of mononuclear and dinuclear cadmium (II) arenedisulfonate complexes with two-to zero-dimensional architectures. Chem. 2002 Sep 23;41(19):4967-74.
- Stoe & Cie, X-Red and X-SHAPE, Stoe & Cie, Darmstadt, Germany, (2002).
- M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).
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