Crystal Growth and Characterization Studies of a Zigzag 1D Sulfonated Coordination Polymer to Prepare Zinc Oxide Nanoparticles

Document Type : Original Research Articles

Authors
shokoofeh Geranmayeh 1
Faezeh Tabesh 2
Alireza Abbasi 2
1 1 Department of Physical Chemistry and Nanochemistry, Faculty of Chemistry, Alzahra University, Tehran, Islamic Republic of Iran
2 2 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran
10.22059/jsciences.2023.348173.1007754
Abstract
Single crystals of a new coordination polymer, {[Zn(2,2’-bipyridine)(H2O)2(1,5-NDS)].2H2O}, where 1,5-NDS is 1,5-naphthalenedisulfonate ion, have been successfully grown under hydrothermal conditions. The as-synthesised coordination polymer was characterised by X-ray Diffraction analysis which shows that the metal centres have been linked by 1,5-NDS linkers and then the structure has extended in a 1D chain. Moreover, the compound was studied using thermogravimetric analysis (TGA) to check its thermal stability and IR spectroscopy.  The prepared compound was a good candidate as a precursor to prepare ZnO nanoparticles. ZnO nanoparticles which were achieved after calcinating the compound, were characterized by Scanning Electron Microscopy (SEM) and PXRD.
Keywords
Coordination polymer
Nanoparticles
Single crystal
Sulfonated
Subjects
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Journal of Sciences, Islamic Republic of Iran
Volume 34, Issue 1
Winter 2023
Pages 27-33